Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing
Patent
1990-08-13
1992-02-11
Hollrah, Glennon H.
Organic compounds -- part of the class 532-570 series
Organic compounds
Amino nitrogen containing
564395, 564399, 564409, C07C20928
Patent
active
050877542
ABSTRACT:
N,N-dialkylanilines can be prepared by reacting the anilines on which they are based with lower alcohols or with the corresponding ethers, at an increased temperature in the gas phase in the presence of a proton-containing zeolite catalyst of the pentasil type having an SiO.sub.2 /Al.sub.2 O.sub.3 ratio of >60, it being advantageous to carry out the alkylation process under a pressure of 2-30 bar.
REFERENCES:
patent: 4801752 (1989-01-01), Chen et al.
Chemical Abstracts, vol. 108, No. 3, 1/18/88, p. 558 ref. no. 21483y Sato Haruhito et al: "Preparation of N-Alkylaniline Derivatives as Intermediates for drugs, agrochemicals, and color photography couplers."
Chemical Abstracts, vol. 84, No. 17, 4/26/76, p. 500 refn no. 121339K Takamiya Nobuo et al: "N-Methylation of Aniline with Methanol over Transition metal Zeolite."
Patent Abstracts of Japan vol. 12, No. 47 (C-475)(2894) 2/12/88 & JP A 62 195350 (Idemitsu Kosan) 8/28/87.
Buysch Hans-Josef
Pelster Heinrich
Puppe Lothar
Wimmer Peter
Bayer Aktiengesellschaft
Hollrah Glennon H.
Kumar Shailendra
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