Process for the preparation of N,N-dialkylaniline

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564395, 564399, 564409, C07C20928

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active

050877542

ABSTRACT:
N,N-dialkylanilines can be prepared by reacting the anilines on which they are based with lower alcohols or with the corresponding ethers, at an increased temperature in the gas phase in the presence of a proton-containing zeolite catalyst of the pentasil type having an SiO.sub.2 /Al.sub.2 O.sub.3 ratio of >60, it being advantageous to carry out the alkylation process under a pressure of 2-30 bar.

REFERENCES:
patent: 4801752 (1989-01-01), Chen et al.
Chemical Abstracts, vol. 108, No. 3, 1/18/88, p. 558 ref. no. 21483y Sato Haruhito et al: "Preparation of N-Alkylaniline Derivatives as Intermediates for drugs, agrochemicals, and color photography couplers."
Chemical Abstracts, vol. 84, No. 17, 4/26/76, p. 500 refn no. 121339K Takamiya Nobuo et al: "N-Methylation of Aniline with Methanol over Transition metal Zeolite."
Patent Abstracts of Japan vol. 12, No. 47 (C-475)(2894) 2/12/88 & JP A 62 195350 (Idemitsu Kosan) 8/28/87.

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