Process for the preparation of muscone

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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549355, C07C 4557

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active

043352626

ABSTRACT:
Process for the preparation of muscone starting from pyranic derivatives by treatments thereof with hydrogen in an inert organic solvent and in the presence of a noble metal catalyst.
Compound of formula ##STR1## and process for its preparation via dehydrogenation and dehydration of corresponding diol.
Process for the preparation of unsaturated macrocyclic ketones of formula ##STR2## wherein the dotted lines stand for a single or a double bond wherein x=1 and y=2, or

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Karpf et al., Chem. Abst., vol. 88, #120885f (1978).
Eschennaser et al., Chem. Abst., vol. 66, #94719d (1966).
Ohloff et al., Chem. Abst., vol. 66, #85512d (1966).
Tetrahidion, vol. 20 (11), pp. 2601-2608 (1964).
Nair et al., J. Chem., Soc., vol. 1964, pp. 4154-4157 (1964).

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