Process for the preparation of mono-alkylcarbonate of bisphenols

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbonate esters

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C07C 6806

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active

056273010

ABSTRACT:
A process for the preparation of mono-alkylcarbonate of bisphenols of the formula ##STR1## wherein R.sub.1 represents ispropylidene, hexa-fluoroisopropylidene, cyclohexane, sulphone, ketone, ether, phthaline, phthalimide and R.sub.2 represents an alkyl group with 1-8 carbon atoms the alkyl group being ethyl, propyl, butyl, hexyl, isopropyl, iso-butyl, tert-butyl, cyclohexyl which comprises reacting bisphenols of the formula ##STR2## where R.sub.1 represents ispropylidene, hexa-fluoroisopropylidene, cyclohexane, sulphone, ketone, ether, phthaline, phthalimide with dialkylcarbonates in presence of a catalyst selected from organometallic compounds of tin and titanium under inert atmosphere at a temperature in the range of 80.degree.-150.degree.C.

REFERENCES:
patent: 4217438 (1980-08-01), Brunelle et al.
patent: 4349486 (1982-09-01), Brunelle et al.
patent: 4973728 (1990-11-01), Tuinstra et al.
patent: 5034557 (1991-07-01), Kiso et al.
patent: 5149856 (1992-09-01), Sch on et al.
patent: 5380908 (1995-01-01), Murata et al.
Buysch, H.J. et al., Derwent Abstract No. 79-16135B; 1979; German Patent Application No. 2736062.

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