Organic compounds -- part of the class 532-570 series – Organic compounds – Thioimidate esters
Patent
1986-02-11
1987-10-06
Ford, John M.
Organic compounds -- part of the class 532-570 series
Organic compounds
Thioimidate esters
564255, 560134, 560132, 560338, 549470, 549452, 549438, C07C11918, C07C13100, C07C12504, C07D30778
Patent
active
046984380
ABSTRACT:
A continuous, close-coupled method for making N-methyl carbamate pesticides which comprises contacting the methyl isocyanate in a vapor phase mixture containing methyl isocyanate and water with a selected oxime or phenol, said mixture being the reaction product formed by oxidizing monomethylformamide. An optional intermediate step for preparing the methyl isocyanate/water vapor phase reaction mixture for contact with the oxime or phenol is to remove therefrom a portion of the water without liquefying the methyl isocyanate by cooling the mixture to a temperature below the dew point of water but above the dew point of the methyl isocyanate.
REFERENCES:
patent: 2870057 (1959-01-01), Hartle et al.
patent: 3506698 (1970-04-01), Jelinek
patent: 3576834 (1971-04-01), Buchanan
patent: 4207251 (1980-06-01), Heyboer
Blaisdell Charles T.
Cordes Walter J.
Heinsohn George E.
Kook John F.
Kosak John R.
Costello James A.
E. I. Du Pont de Nemours and Company
Ford John M.
Whittenbaugh Robert C.
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