Process for the preparation of methyl carbamates and thioimidate

Organic compounds -- part of the class 532-570 series – Organic compounds – Thioimidate esters

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564255, 560134, 560132, 560338, 549470, 549452, 549438, C07C11918, C07C13100, C07C12504, C07D30778

Patent

active

046984380

ABSTRACT:
A continuous, close-coupled method for making N-methyl carbamate pesticides which comprises contacting the methyl isocyanate in a vapor phase mixture containing methyl isocyanate and water with a selected oxime or phenol, said mixture being the reaction product formed by oxidizing monomethylformamide. An optional intermediate step for preparing the methyl isocyanate/water vapor phase reaction mixture for contact with the oxime or phenol is to remove therefrom a portion of the water without liquefying the methyl isocyanate by cooling the mixture to a temperature below the dew point of water but above the dew point of the methyl isocyanate.

REFERENCES:
patent: 2870057 (1959-01-01), Hartle et al.
patent: 3506698 (1970-04-01), Jelinek
patent: 3576834 (1971-04-01), Buchanan
patent: 4207251 (1980-06-01), Heyboer

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