Process for the preparation of methyl 3,4-anhydro-2,6-dideoxy-L-

Details Process for the preparation of methyl 3,4-anhydro-2,6-dideoxy-L- Process for the preparation of methyl 3,4-anhydro-2,6-dideoxy-L-

1979-06-13

1980-10-14

Chan, Nicky

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07D31100

Patent

active

042280800

ABSTRACT:
A process to produce methyl 3,4-anhydro-2,6-dideoxy-L-ribohexopyranoside, its enantiomer and racemate thereof.
The compound is useful as an intermediate in the production of daunosamine which in turn is a prime constituent in the anti-cancer agents Daunomycin and Adriamycin. Also disclosed are novel intermediates in the process.

REFERENCES:
Shono et al., Tetrahedron Letters, 17, 1363 (1976).
Marsh et al., Chem. Comm., 1967, 973.
Gupta, Carbohydrate Res., 37, 381 (1974).
Stevens et al., J. Org. Chem., 40, 3704 (1975).
Horton et al., Carbohydrate Res., 44, 227 (1975).
Action et al., J. Med. Chem., 17, 659 (1974).

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