Process for the preparation of methyl 3,4-anhydro-2,6-dideoxy-L-

Details Process for the preparation of methyl 3,4-anhydro-2,6-dideoxy-L- Process for the preparation of methyl 3,4-anhydro-2,6-dideoxy-L-

1980-10-17

1982-01-12

Milestone, Norma S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07D49304

Patent

active

043104622

ABSTRACT:
A process to produce methyl 3,4-anhydro-2,6-dideoxy-L-ribohexopyranoside, its enantiomer and racemate thereof.
The compound is useful as an intermediate in the production of daunosamine which in turn is a prime constituent in the anti-cancer agents Daunomycin and Adriamycin. Also disclosed are novel intermediates in the process.

REFERENCES:
patent: 3052592 (1962-09-01), Phillips et al.
R. Bonjouklian et al., J. Org. Chem. (1977), vol. 42 (25), pp. 4095-4103.
F. Korte et al., Tetrahedron, vol. 18 (1962), pp. 1257-1264.
Chemical Abstracts, 7th Coll. Index, p. 7606s.

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