Chemistry: fischer-tropsch processes; or purification or recover – Liquid phase fischer-tropsch reaction
Patent
1997-12-12
1999-09-28
Killos, Paul J.
Chemistry: fischer-tropsch processes; or purification or recover
Liquid phase fischer-tropsch reaction
518715, 502324, 502325, C07C 2700, B01J 2332, B01J 2300
Patent
active
059589850
ABSTRACT:
A process for the preparation of hydrocarbons by catalytic reaction of carbon monoxide with hydrogen in which reaction a feed comprising hydrogen and carbon monoxide is contacted at elevated temperature and pressure with a catalyst comprising cobalt and manganese in which catalyst the cobalt/manganese molar ratio is between 14:1 and 7:1 and the GHSV is at least 1600 N1/1/h. Preferably the cobalt/manganese molar ratio is between 13:1 and 9:1 and the GHSV is between 2700 and 25,000 N1/1/h. The reaction is especially carried out in a slurry phase regime.
REFERENCES:
patent: 4463101 (1984-07-01), Dwyer et al.
patent: 4874732 (1989-10-01), Miller
patent: 5162284 (1992-11-01), Soled et al.
Geerlings Jacobus Johannes Cornelis
Hoek Arend
Huisman Hans Michiel
Lednor Peter William
Killos Paul J.
Parsa J.
Shell Oil Company
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