Process for the preparation of higher alkenes

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – From nonhydrocarbon feed

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585469, C07C 100

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active

042490294

ABSTRACT:
A process for the preparation of a straight-chain or branched alkene which has 20 to 24 carbon atoms and in which the ethylenic bond is located after a carbon atom numbered between 8 and 11, which process comprises reacting, in an anhydrous solvent, preferably in an oxahydrocarbon an organometallic copper compound with an alkyl or alkenylsulfonate.

REFERENCES:
patent: 3546106 (1970-12-01), Blytas
patent: 3597460 (1971-08-01), Thompson
patent: 3948803 (1976-04-01), Carney
Tetrahedron Letters, No. 42, pp. 3695-3698, 1977.

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