Process for the preparation of hex-2-enal

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260610B, C07C 4720

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active

040284204

ABSTRACT:
The rate of palladium catalyzed deperoxidation of cyclohexyl hydroperoxide to form hex-2-enal is increased by carrying out the deperoxidation using an aqueous solution containing both a palladium derivative and a derivative of divalent iron.

REFERENCES:
patent: 2694090 (1954-11-01), Wild
patent: 3497561 (1970-02-01), Gelbein
patent: 3839457 (1974-10-01), Joufrett
Swern, Organic Peroxides, vol. II, pp. 157-159.
Farkas et al., "J.A.C.S." vol. 72, (1933), pp. 3333-3337.
Tobolsky, Organic Peroxides, pp. 117-119.

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