Process for the preparation of formamides

Details Process for the preparation of formamides Process for the preparation of formamides

1976-12-27

1978-06-27

Demers, Arthur P.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

26029386, 260562R, 260557R, C07C10302

Patent

active

040975240

ABSTRACT:
A process for the preparation of formamides by reacting a tertiary amine with carbon monoxide in the presence of a solvent, a catalytic quantity of a copper salt and oxygen or an oxygen-containing gaseous mixture. The reaction is preferably carried out in the presence of excess amine, a volatile alcohol solvent, and a copper halide catalyst.

REFERENCES:
patent: 2677706 (1954-05-01), Giachino
patent: 2793211 (1957-05-01), Locicero et al.
patent: 3099689 (1963-07-01), Cragg
patent: 3412150 (1968-11-01), Nozaki
patent: 3446842 (1969-05-01), Nozaki
patent: 3530182 (1970-09-01), Haynes et al.
Beckwith, The Chemistry of Amides; Interscience Publishers, N.Y., N.Y., 1970, p. 118.
Saegusa et al. Tet. Letters, 1966, #49, pp. 6125-6129.
Saegusa et al., Bull. Chem. Soc. Japan 42 (1969), pp. 2610-2614.
Nefedov et al. Izv. Akad. Nauk; S.S.S.R., Ser Khim #7, 1973, pp. 1536-1550.

Affiliated with

Also associated with

Rating

Process for the preparation of formamides does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for the preparation of formamides, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for the preparation of formamides will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-2304126