Process for the preparation of fluorine containing crosslinked e

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528401, 528422, 528423, C08G 6344

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042424984

ABSTRACT:
New crosslinked elastomeric polytriazines have been prepared by a 4-step procedure which consists of: (1) forming a poly(imidoylamidine) by the reaction under reflux conditions of anhydrous ammonia with certain perfluorinated alkyl or alkylether dinitriles; (2) forming a linear polytriazine by cyclizing the imidoylamidine linkages by reaction with certain perfluorinated alkyl or alkylether acid anhydrides or halides; (3) extending the linear polytriazine chain by further refluxing in anhydrous ammonia; and (4) heating to cyclize the new imidoylamidine linkages and thereby crosslink the polymer.

REFERENCES:
Fluoropolymers, High Polymers, vol. XXV, 1972, Wall, pp. 267-289, 307-315.

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