Process for the preparation of expandable polystyrene

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Cellular products or processes of preparing a cellular...

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521 59, 521 60, C08J 918, C08J 920

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055917780

ABSTRACT:
The invention relates to a process for the preparation of bead shaped, expandable polystyrene by the polymerization of styrene in an aqueous suspension in the presence of dimeric .alpha.-methylstyrene as a regulator and a C.sub.3 to C.sub.6 hydrocarbon as a blowing agent, whereby one first reports the content of saturated hydrocarbons, having a boiling point between 70.degree. and 170.degree. C., in the styrene and dimeric .alpha.-methylstyrene, and then enough saturated hydrocarbons, having a boiling point from 70.degree. to 170.degree. C., are added before, during or after the polymerization so that their total content in the suspension is from 0.1 to 0.8 weight percent, based on the styrene.

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