Process for the preparation of dioldiones

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260590R, 260592, 260594, C07C 4516, C07C 4500

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active

040013332

ABSTRACT:
A dioldione represented by the formula: ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, the same or different, represent alkyl, cycloalkyl, arylalkyl, aryl or hydrogen, is prepared by reacting a compound represented by the formula: ##STR2## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 have the above meanings, with an oxidizing mixture consisting of osmium tetroxide and an alkali or alkali-earth metal chlorate.

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Hofmann, "Ber.", vol. 45, pp. 3329-3336 (1912).
Zelekoff et al., "J.A.C.S.", vol. 72, pp. 5039-5042 (1950).
Re et al., "Helv", vol. 56, pp. 1882-1894 (1973).

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