Process for the preparation of dimethyl carbonate

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbonate esters

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558260, C07C 6996

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active

054987440

ABSTRACT:
Dimethyl carbonate is obtained with a high selectivity and great constancy over time by reacting carbon monoxide with methyl nitrite in a continuous gas phase reaction in the presence of a heterogeneous catalyst prepared by the application to a suitable support of one or more palladium compounds of the formula

REFERENCES:
patent: 5214184 (1993-05-01), Matuzaki et al.
patent: 5231213 (1993-07-01), Landscheidt et al.
Chinese paper with English Abstract entitled "Research Of A New Method Of Synthesis Of Dimethyl Carbonate:, Jiang Xuan-zhen, Zhu Yong-bao (Department of Chemistry, Zhejang University, Hangzhou) and Xu Song-yan (Fujian Institute of Research on the Structure of Matter, Academia Sinica," Fuzhou (1989)).

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