Process for the preparation of dimerization products from olefin

Details Process for the preparation of dimerization products from olefin Process for the preparation of dimerization products from olefin

1985-10-03

1986-07-08

Davis, Curtis R.

Chemistry of hydrocarbon compounds

Unsaturated compound synthesis

By addition of entire unsaturated molecules, e.g.,...

585510, C07C 226

Patent

active

045994765

ABSTRACT:
A process for the preparation of dimerization products from aliphatic mono-olefins having 2 to about 12 carbon atoms in which the aliphatic mono-olefin is contacted with a catalytic system formed by combining a palladium and/or ruthenium compound and an acid with a pKa of less than 2, except hydrohalogenic acids in an aprotic organic solvent.

REFERENCES:
Chem. Abstr. 90 22286 h (1979).
J. Am. Chem. Soc. 103 4627-4629 (1981) and 104 3520-3522 (1982).
Transition Metal Catalyzed Polymerization; Alkenes and Dienes, Part A, ed. by R. P. Quirk, 1983, pp. 341-354.
Angew, Chem. Int. Ed. 14 (1975) 104-105.

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