Process for the preparation of dialkyltin dialkoxide

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

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502 20, 502 22, 502161, 502170, 502171, 556 88, 556 89, B01J 3122

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active

055456006

ABSTRACT:
A process for making a catalyst product which comprises reacting dialkyltin oxide with an alcohol and the corresponding dialkyl carbonate at a temperature in the range between about 50.degree. to 200.degree. C. and at a pressure in the range between about 75 to 600 psi (0.52 to 4.14 MPa), wherein the catalyst product comprises dialkyltin dialkoxide in the range between about 90 to 100 mole % based on the tin species of the catalyst product. This process also forms effective catalyst product when the methanol is replaced with either a primary or secondary alcohol.

REFERENCES:
patent: 2583084 (1952-01-01), Burt
patent: 2700675 (1955-01-01), Mack et al.
patent: 2727917 (1955-12-01), Mack et al.
patent: 3492327 (1970-01-01), Davies
patent: 5034551 (1991-07-01), Vernon et al.
patent: 5374754 (1994-12-01), Hoenel et al.
Davies et al., "Organotin Chemistry. Part XI. The Preparation of Organotin Alkoxides", Journal of Chemical Society, 1971, pp. 3972-3976. (month unknown).
M. G. Voronkov and Yu. P. Romadan, New Method for the Synthesis of Dialkoxydialkyltins, Zhurnal Obshchei Khimii, vol. 39, No. 12, pp. 2785-2786, Dec. 1969.

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