Process for the preparation of di- and polyamines of the...

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

Reexamination Certificate

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C560S347000, C564S315000

Reexamination Certificate

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11392367

ABSTRACT:
Di- and polyamines of the diphenylmethane series are prepared by a) mixing a first portion of aniline with an acid catalyst, b) mixing a second portion of aniline with formaldehyde, and c) mixing and reacting the mixtures prepared in each of steps a) and b). The diamines produced by this process may then be phosgenated to produce the corresponding di-/polyisocyanate.

REFERENCES:
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patent: 5310769 (1994-05-01), Konig et al.
patent: 6433219 (2002-08-01), Ströfer et al.
patent: 6831192 (2004-12-01), Ströfer et al.
patent: 2002/0132953 (2002-09-01), Strofer et al.
patent: 2004/0171869 (2004-09-01), Reif et al.
patent: 2005/0014975 (2005-01-01), Strofer et al.
Chem. Soc. Rev., 3(2), (month unavailable) 1974, p. 209-230, H.J. Twitchett, “Chemistry of the Production of Organic Isocyanates”.
Kirk-Othmer Encycl. Chem. Technol., 3rded., 2, (month unavailable) 1978, pp. 338-348, M.V. Moore, “Methylenedianiline”.
Wissenschaftliche Zeitschrift der TU Dresden, 38 (month unavailable) 1989, pp. 121-126, “Einfaches kinetisches Modell der Anilin-Formaldehyd-Kondensation”.

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