Process for the preparation of cyclopentadienyltrialkoxytitanium

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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526943, 502103, 502152, C07F 1700, C07F 728

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active

056250860

ABSTRACT:
The invention relates to a process for the preparation of cyclopentadienyltrialkoxy derivatives of the general formula

REFERENCES:
G. Llinas et al., "(C.sub.5 Me.sub.5)SiMe.sub.3 as a mild and effective reagent for transfer of the C.sub.5 Me.sub.5 ring: an improved route to monopentamethylcyclopentadienyl trihalides of the group 4 elements", 1988, Journal of Organometallic Chemistry, 340:37-40.
P.C. Wailes et al., Organometallic Chemistry of Titanium, Circonium, and Hafnium, 1974, 34-39.
R.B. King et al., "Organometallic Chemistry of the Transition Metals XXI. Some .pi.-Pentamethylcyclopentadienyl Derivatives of Various Transition Metals", 1967, J. Organometal. Chem. 8:287-297.
H. Rohl, et al., "Pentamethyl-cyclopentadienyl-titantrichlorid", 1962, Angew. Chem., p. 155.
A.N. Nesmeyanov, et al., "Reaction of cyclopentadienylsodium with alkoxytitanium chlorides", 1961, Alicylic Compounds, pp. 6397-6398.
A.N. Nesmeyanov, et al., "Mono-.pi.-cyclopentadienyl derivatives of titanium", 1961, Heterocyclic Compounds, pp. 22273-22274.
Ulf Thewalt, "Titan-Organische Verbindungen", 1977, Gmelin Handbuch der Anorganischen Chemie, pp. 136-156.

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