Process for the preparation of chlorodeoxysugars

Details Process for the preparation of chlorodeoxysugars Process for the preparation of chlorodeoxysugars

1980-03-05

1982-04-13

Hazel, Blondel

Organic compounds -- part of the class 532-570 series

Organic compounds

Carbohydrates or derivatives

536119, C07H 502

Patent

active

043248888

ABSTRACT:
A process for the preparation of a chlorodeoxy derivative of a reducing aldose having a primary hydroxy group in an exocyclic -CH.sub.2 OH group, in which the said primary hydroxy group is replaced by a chlorine atom to give a chlorodeoxy reducing sugar with a free anomeric center, characterized in that the free reducing sugar is reacted with a reagent comprising an N,N-dialkyl (methaniminium) chloride obtained by reacting an N,N-dialkyl formamide with a chlorinating agent.

REFERENCES:
patent: 4117224 (1978-09-01), Khan et al.

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