Process for the preparation of ceric hydrocarbyl silyloxides by

Details Process for the preparation of ceric hydrocarbyl silyloxides by Process for the preparation of ceric hydrocarbyl silyloxides by

1987-12-03

1991-05-21

Maples, John S.

Organic compounds -- part of the class 532-570 series

Organic compounds

Rare earth containing

C07F 500

Patent

active

050176943

ABSTRACT:
A process is provided for preparing ceric hydrocarbyl silyloxides, which comprises transetherifying a ceric alkoxide with the silanol having the desired hydrocarbyl group and the desired number of hydroxyl groups under anhydrous conditions at a temperature within the range from about -30.degree. C. to about 200.degree. C., thereby displacing the aliphatic alcohol of the alkoxide and forming the ceric hydrocarbyl silyloxide of the silanol.

REFERENCES:
patent: 3267036 (1964-08-01), Baker et al.
patent: 3884950 (1975-05-01), Koda et al.
patent: 4070343 (1978-12-01), Kishimoto et al.
patent: 4489000 (1984-12-01), Gradeff et al.
patent: 4663439 (1987-05-01), Gradeff et al.
Rad'Kov et al., Journal of the General Chemistry of the U.S.S.R., (1986), pp. 336-338.
Batwara et al., Journal of Inorganic Nuclear Chemistry, (1970), pp. 411-415.

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