Process for the preparation of cationized polyvinyl alcohol

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525 62, 525374, C08F 800

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active

048228516

ABSTRACT:
A process for the preparation of cationized polyvinyl alcohol (PVA) by reaction of alkylidene epoxides with PVA in alkaline medium in the presence of water, in which the reaction mixture contains 11 to 30 weight % of water, based on its total amount, and 1 to 4 weight % of an alkali metal or alkaline earth metal hydroxide or alkaline earth metal oxide, based on the quantity of PVA. As the cationizing agent there are used alkylidene epoxides or their mixtures having the general formula ##STR1## wherein n - 1, 2 or 3, R.sub.1, R.sub.2 and R.sub.3 represent the same or different alkyl residues having 1 to 18 carbon atoms or R.sub.1 represents the benzyl or --C.sub.2 H.sub.4 OH, and X.sup.- denotes chloride, bromide, sulfate or acetate.

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