Process for the preparation of carboxylic esters defined from al

Details Process for the preparation of carboxylic esters defined from al Process for the preparation of carboxylic esters defined from al

1995-05-05

1996-09-10

Shippen, Michael L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

C07C 6705

Patent

active

055547869

ABSTRACT:
A process which comprises reacting an aliphatic or cycloaliphatic olefin, having 4 to 16 carbon atoms in its main chain and a non-terminal double bond, with a carboxylic acid, in the presence of hydrogen peroxide and a catalyst consisting of a palladium salt or complex.

REFERENCES:
Hansson et al.; "Preparation of Allylic Acetates from Simple Alkenes by Palladium (II)--Catalyzed Acetoxylation", J. Org. Chem. 1990, 55, 975-984.
Greenberg et al.; "Iron Phthalocyanine as a Catalyst for the Aerobic Oxidation of Hydroquinone to 1,4-Benzoquinone. A Simple Test for Catalytic `Oxidase` Activity", Acta Chemica Scandinavica 47 (1993) 506-508.
Larsson et. al.; "A Catalytic System for Allylic Acetoxylation Consisting of Palladium (II) and Nitrate and Using Oxygen as Final Oxidant", Tetrahedron Letters, vol. 34, No. 15 pp. 2523-2526, 1993.
Backvall et al.; "Multistep Electron Transfer in Palladium-Catalyzed Aerobic Oxidations via a Metal Macrocyle-Quinone System"; J. Am. Chem. Soc. 1990, 112, 5160-5166.
Grennberg et al.; "Use of Sulfoxides as Cocatalysts in the Palladium-Quinone-Catalyzed 1, 4 Diacetoxylation of 1,3-Dienes. An Example of Ligand-Accelerated Catalysis"; J. Org. Chem. 1991, 56, 5808-5811.

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