Process for the preparation of .beta.-phenylisoserine and .beta.

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C07D20500

Patent

active

059395613

ABSTRACT:
The present invention relates to new process for the preparation of .beta.-phenylisoserine and its analogues of general formula: ##STR1## which are particularly useful for preparing taxane derivatives which have remarkable antitumour and antileukaemic activities.

REFERENCES:
patent: 4924012 (1990-05-01), Colin et al.
patent: 5041643 (1991-08-01), Tinti et al.
patent: 5175315 (1992-12-01), Holton
patent: 5294737 (1994-03-01), Ojima
patent: 5304670 (1994-04-01), Correa et al.
I. Ojima et al., "Azetidines and Bisazetidines. Their Synthesis and Use as the Key Intermediates to Enantiomerically Pure Diamines, Amino Alcohols, and Polyamines", Journal of Organic Chemistry vol. 56 (1991) pp. 5263-5277.
Brieva et al., "Chemoenzymatic Syntheis of the C-13 Side Chain of Taxol: Optically-Active 3-Hydroxy-4-phenyl.beta.-Lactam Derivatives", J. Org. Chem.; vol. 58 (1993) pp. 1068-1075.
Ojima et al., "New and Efficient Approaches to the Semisynthesis of Taxol and its C-13 Side Chain Analogs by Means of .beta.-Lactam Synthon Method", Tetrahedron vol. 48, (1992) pp. 6985-7012.
Chemical Abstracts, vol. 118:80677u & 80679w (1993) p. 808.
Ojima et al., "Efficient and Practical Asymmetric Synthesis of the Taxol C-13 Side Chain, N-Benzoyl-(2R, 3S)-3-phenylisoserine, and Its Analogues via Chiral 3-Hydroxy-4-aryl-.beta.-lactams through Chiral Ester Enolate-Imine Cyclocondensation", J. Org. Chem., vol. 56 (1991) pp. 1681-1683.
Furukawa et al., A Steroselective Synthesis of .alpha.-Chloro-.alpha.-phenylacetamide by the Reaction of Optically Active Schiff Base with Dichlorocarbene, Chem. Pharm. Bull., vol. 25, (1977) pp. 181-184.
Palomo et al. "Highly Steroselective Synthesis alpha-Hydroxy beta-Amino acids through beta-Lactams: Application to the Synthesis of the Taxol and Bestatin Side Chains and Related Systems", Tetrahedron Letters, vol. 31, No. 44. pp. 6429-6432, 1990.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Process for the preparation of .beta.-phenylisoserine and .beta. does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for the preparation of .beta.-phenylisoserine and .beta., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for the preparation of .beta.-phenylisoserine and .beta. will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-315977

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.