Process for the preparation of aryl substituted aldehydes, keton

Details Process for the preparation of aryl substituted aldehydes, keton Process for the preparation of aryl substituted aldehydes, keton

1975-06-16

1978-01-24

Mars, Howard T.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260590R, 260590D, 260590C, 260590E, 260599, 260618R, 260613D, 26034611, 260465R, 260465F, 260558R, 260515R, 560130, 560 51, C07D31706

Patent

active

040703746

ABSTRACT:
Upon reacting an alcohol having an olefinic double bond with an aryl bromide or iodide in the presence of a Paladium catalyst, there is provided either an aryl substituted aldehyde, ketone or olefinic alcohol.

REFERENCES:
patent: 3527794 (1970-09-01), Heck
patent: 3767710 (1973-10-01), Heck
patent: 3922299 (1975-11-01), Heck
Dieck et al., J.A.C.S., vol. 94, pp. 1133-1136, (1974).
Heck, J.A.C.S., vol. 93, pp. 6896-6901, (1971).
Heck et al., J. Org. Chem., vol. 37, pp. 2320-2322, (1972).
Heck, J.A.C.S., vol. 90, pp. 5526-5531, 5535-5538, 5518-5525, (1968).
Dieck et al., J.A.C.S., vol. 96, pp. 1133-1136, (1974).
Danno, J. Chem. Soc. (B), (1971), pp. 196-198.

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