Process for the preparation of aromatic polyimide film

Plastic and nonmetallic article shaping or treating: processes – Forming continuous or indefinite length work – By casting liquids on a solid supporting or shaping surface

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264204, 264236, 26433121, 264347, 26433119, 528188, 528353, B29C 3914

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active

053085698

ABSTRACT:
A process for the preparation of an aromatic polyimide film includes the steps of casting a polyamide acid solution containing an imidization agent on a support in the form of a film, heating the filmy cast solution on the support at a temperature of 80.degree. to 200.degree. C. to obtain a self-supportable film; peeling the self-supportable film from the support; and further heating the film at a temperature of not lower than 300.degree. C. The polyamide acid solution includes a polyamide acid obtained by polymerization reaction of 3,4,3',4'-biphenyltetracarboxylic dianhydride and p-phenylenediamine in a mixture of a polar organic solvent and a small amount of an imidization agent selected from imidazole, a substituted imidazole, benzimidazole, a substituted benzimidazole, isoquinoline, and a substituted pyridine.

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patent: 5037587 (1991-08-01), Saruwatari et al.

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