Process for the preparation of aqueous ammonium thiocyanate solu

Chemistry of inorganic compounds – Nitrogen or compound thereof – Carbon containing

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C01C 320

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active

050265342

ABSTRACT:
Aqueous ammonium thiocyanate solutions are prepared continuously by reaction of ammonia with carbon disulfide in the presence of water using activated carbon as catalyst at pressures of from 2 to 7 bar. In this way, a very pure product can be obtained. The process can be carried out at very low cost, because both the addition of ammonia to carbon disulfide and the decomposition of the resulting ammonium dithiocarbamate can be carried out in a reactor in one step under identical conditions.

REFERENCES:
patent: 2249962 (1941-07-01), Lento, Jr. et al.
patent: 2286273 (1942-06-01), Hill
patent: 2850356 (1958-09-01), Sutherland et al.
patent: 3615177 (1971-10-01), Magerlein et al.

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