Process for the preparation of an alkoxylated alcohol...

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C518S700000, C518S715000, C510S524000

Reexamination Certificate

active

07105706

ABSTRACT:
Process for the preparation of an alkoxylated alcohol composition comprising one or more alkoxylated alcohols wherein the process comprises the steps of:(a) reacting carbon monoxide with hydrogen under Fischer-Tropsch reaction conditions in the presence of a Fischer-Tropsch catalyst;(b) separating from the product of step (a) at least one hydrocarbon fraction comprising paraffins having from 9 to 17 carbon atoms and olefins having from 9 to 17 carbon atoms, the hydrocarbon fraction additionally comprising at least a portion of alcohols;(c) contacting one or more of the hydrocarbon fractions obtained in step (b) with an alkylene oxide; and(d) recovering an alkoxylated alcohol composition from the reaction product of step (c).

REFERENCES:
patent: 5057627 (1991-10-01), Edwards
patent: 5907067 (1999-05-01), Barnhorst et al.
patent: 6706931 (2004-03-01), Edwards
patent: 6740683 (2004-05-01), Price
patent: 2003/0018086 (2003-01-01), Price
patent: 00/14045 (2000-03-01), None
patent: 345861 (1989-12-01), None
patent: 02/47817 (2002-06-01), None
patent: 2 483 470 (2003-11-01), None
A.P. Steynberg, R.L. Espinoza, B. Jager, A.C. Vosloo, “High Temperature Fischer-Tropsch synthesis in commercial practice”, Applied Catalysis A:General 186(1999), pp. 41-54.
Frohning et al in Falbe; Chemical Feedstocks from Coal; Chapter 8; Fischer-Tropsch Process, pp. 309-432, John Wiley & Sons, 1982.

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