Process for the preparation of .alpha.-aminoalkylphosphonic acid

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus esters

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562 15, C07F 940, C07F 946

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active

049609203

ABSTRACT:
.alpha.-Aminoalkylphosphonic and .alpha.-aminoalkylphosphinic acids of the formula I ##STR1## where n=1 or 0,

REFERENCES:
patent: 2754320 (1956-07-01), Johnston
patent: 2953595 (1960-09-01), Rauhut et al.
patent: 3980614 (1976-09-01), Noetzel et al.
patent: 3980615 (1976-09-01), Noetzel
patent: 4105689 (1978-08-01), Auer et al.
patent: 4886628 (1989-12-01), Kleiner
The Merck Index, 6th ed. (1952), pp. 1060 and 1061.
Organic Reactions, 3 (1946), p. 267 ff., "The Hoffmann Reaction", p. 268 (Wallis et al.).
Rachon et al., "Aminophosphonic Acids; Hofmann Degradation of Carboxamides-A New Method of the Preparation of Alpha-Aminophosphonic Acids", Z. Chem., 14, No. 4, pp. 152-154 (1974).
Chemical Abstracts, 81, No. 63728m, p. 484 (1974).
Article by L. Maier, "Advances in the Chemistry of Aminophosphinic Acids" in the journal Phosphorus and Sulfur, 1983, vol. 14, pp. 295-322.
Hofmann Degradation and Bromination of Amides derived from Phosphonoacetic Acid (Tetrahedron Letters, No. 52, pp. 5201-5202, 1973).
J. Org. Chem, 23, pp. 1888-1886) (1958).

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