Process for the preparation of alkylene glycols

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C568S680000

Reexamination Certificate

active

07098367

ABSTRACT:
Disclosed is a process for the preparation of alkylene glycols from the corresponding alkylene oxide, such as ethylene glycol from ethylene oxide, in the presence of water, a catalyst and, optionally, carbon dioxide. The catalyst contains amines which are weak bases, specifically having pKaof at least 5.5, preferably 8 to 11. The amines may be primary, secondary, tertiary or a blend thereof or may be a compound having a structural combination of primary, secondary and/or tertiary amines.

REFERENCES:
patent: 4243759 (1981-01-01), Haas
patent: 4307256 (1981-12-01), Cipriani et al.
patent: 4393254 (1983-07-01), Johnson et al.
patent: 4521548 (1985-06-01), Christen et al.
patent: 6137015 (2000-10-01), Strickler et al.
John H. Biel; Antihistaminics. I. Some Ethylene Diamines and an Aminoether; J. Am. Chem. Soc., vol. 71, issue 4, p. 1306-1309 (Apr. 1949).

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