Process for the preparation of alkylated glycosyl fluorides free

Details Process for the preparation of alkylated glycosyl fluorides free Process for the preparation of alkylated glycosyl fluorides free

1986-08-07

1989-02-07

Griffin, Ronald W.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carbohydrates or derivatives

536 22, 536124, C07H 1500, C07H 1900, C07H 2100

Patent

active

048032638

ABSTRACT:
Alkylated glycosyl fluorides free from hydroxyl groups can be prepared by converting glycosyl fluorides which still contain hydroxyl groups into the alkylated compounds in the manner of Williamson's ether synthesis in the presence of basic systems by means of alkylating agents.

REFERENCES:
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patent: 4719294 (1988-01-01), Rademacher et al.
R. J. Ferrier, "Methds in Carbohydrate Chemistry", vol. 6, 1972, pp. 307-311.
J. E. G. Barnett, Carbohydrate Research, vol. 9, 1969, pp. 21-31.
Chemical Abstracts No. 186733k, vol. 104, No. 21, May 26, 1986.
Windholz et al., "The Merck Index", ONR-96.
Journal of the Chemical Society, Chemical Communications, No. 17, 1984, pp. 1155-1156.
Hayashi et al., Simple Synthesis of Glycosyl Fluorides, pp. 1747-1750.
Klemer et al., Chemische Berichte, 96, 1963, p. 1974.

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