Process for the preparation of acyloxybenzenesulfonic acids and

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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560142, C07C30958, C07C30306, C07C30332

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active

051005883

ABSTRACT:
The process for the preparation of acyloxybenzenesulfonic acids of the general formula ##STR1## in which R denotes a (C.sub.1 -C.sub.17)-alkyl or (C.sub.2 -C.sub.17)-alkenyl radical, or alkali metal, alkaline earth metal or ammonium salts thereof, is carried out in the following stages: (a) sulfonation of phenol, (b) heat treatment of the phenolsulfonic acid formed as the intermediate product, (c) esterification of the phenolsulfonic acid and, if appropriate, (d) neutralization of the resulting (C.sub.2 -C.sub.18)-acyloxybenzenesulfonic acid. As a result of the incorporation of stage (b), the process affords products in which the proportion of the 1,4-isomer compared with the 1,2-isomer is markedly increased, as a result of which these products can be used, in particular, as perborate activators in detergents.

REFERENCES:
patent: 3320292 (1967-05-01), Cahn et al.
patent: 3394155 (1968-07-01), Cahn et al.
patent: 3503888 (1970-03-01), Miller et al.

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