Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof
Patent
1995-09-27
1997-09-02
Conrad, Joseph
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acids and salts thereof
C07C 5112
Patent
active
056634293
ABSTRACT:
A process for preparing acetic acid from methanol and carbon monoxide or a mixed gas of carbon monoxide with hydrogen, which process comprises contacting methanol with a gaseous component selected from a group consisting of carbon monoxide and a mixed gas of carbon monoxide with hydrogen of 2% by volume or less in the presence of a carbon-supported rhodium metal catalyst and methyl iodide promoter in vapor phase under the conditions of a reaction temperature of 180.degree.-220.degree. C., a reaction pressure of 5-10 kg/cm.sup.2 .multidot.G, and a weight of catalyst to feed gas flow rate ratio (W/F) of 10-20 g.multidot.h/mole; and a process for preparing acetic acid from methanol and carbon monoxide, which process comprises contacting methanol with carbon monoxide in the presence of a carbon-supported rhodium metal catalyst, methyl iodide promoter and water in vapor phase.
REFERENCES:
patent: 3717670 (1973-02-01), Schultz
patent: 4110359 (1978-08-01), Marion
patent: 4111982 (1978-09-01), Eubanks et al.
patent: 4994608 (1991-02-01), Torrence et al.
Proceedings of the 9th International Catalyst Congress, Fujimoto et al: Effect of Hydrogen On Vapor Phase Carbonylation of Methanol, vol. 3, 1988, pp. 1051-1058.
Konishi Yasuo
Uchida Hiroshi
Yamaseki Ken-ichi
Conrad Joseph
Tokyo Gas Company Ltd.
LandOfFree
Process for the preparation of acetic acid does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Process for the preparation of acetic acid, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for the preparation of acetic acid will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-310379