Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus esters
Patent
1985-06-10
1987-03-31
Sutto, Anton H.
Organic compounds -- part of the class 532-570 series
Organic compounds
Phosphorus esters
558169, C07F 940
Patent
active
046544291
ABSTRACT:
A process for the preparation of a glyphosate product. An .alpha.-substituted N-phosphonomethylamino diacetic acid substrate is contacted in an aqueous medium with molecular oxygen in the presence of a catalyst for the oxidative cleavage of a substituent from the imino nitrogen of the substrate. Cleavage produces a glyphosate product, carbon dioxide, a higher aldehyde, or ketone. Novel intermediates and methods of preparation thereof are also disclosed.
REFERENCES:
patent: 3275677 (1966-09-01), Allen, Jr. et al.
patent: 3969398 (1976-07-01), Hershman
Wagner et al., "Synthetic Organic Chemistry (1951), pp. 412-413, 604-605, 669.
Balthazor Terry M.
Pulwer Mitchell J.
Loyer Raymond C.
Monsanto Company
Shearin Frank D.
Sutto Anton H.
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