Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – And additional al or si containing component
Patent
1992-03-03
1993-05-04
Dees, Carl F.
Catalyst, solid sorbent, or support therefor: product or process
Zeolite or clay, including gallium analogs
And additional al or si containing component
502 81, 502 84, B01J 2116, B01J 3700
Patent
active
052081958
ABSTRACT:
A catalyst of a phosphoric acid treated carrier formed from clay minerals and silica gel for the hydration of a C.sub.2-3 olefin to an alcohol is prepared by acid treating an essentially montmorillonite-containing clay contaminated with not more than 3% of extraneous materials until an acid treated clay is obtained having a 10-20% by weight Al.sub.2 O.sub.3 content and a specific surface area of 200 to 400 m.sup.2 /g, adding from 20 to 40 parts by weight of finely particulate silica gel having a particle size distribution of between 30 and 60.times.10.sup.-6 m, a pore volume of 0.9 to 1.7 ml/g and a specific surface are of 200 to 500 m.sup.2 /g and from 1.5 to 2.5 parts by weight of titanium dioxide, each based on total dry substance, to said acid treated clay, shaping the acid treated material to a total water content of 40 to 60% by compression, calcining the shaped material at 500.degree. to 900.degree. C., in a second stage, acid treating the calcined material with acid until it has an Al.sub.2 O.sub.3 content of 1 to 4% by weight and has a specific surface area of 180 to 250 m.sup.2 /g and a pore volume of between 0.8 to 1.5 ml/g, and impregnating the acid treated material with phosphoric acid.
REFERENCES:
patent: 2713560 (1955-07-01), Morrell
patent: 2862875 (1958-12-01), Morrell
patent: 3311568 (1967-03-01), Klimenko et al.
patent: 4808559 (1989-02-01), Sommer et al.
Baumeister Franz-Josef
Schlueter Dietrich
Schubert Klaus-Peter
Dees Carl F.
Huels Aktiengesellschaft
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