Process for the preparation of 7-amino syn 3,5-dihydroxy...

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

Reexamination Certificate

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Reexamination Certificate

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10481704

ABSTRACT:
The invention relates to novel synthesis methods for the preparation of the intermediates, which are suitable for the preparation of statin derivatives, especially to novel synthesis methods of the intermediate of formula VI wherein Raand Rcare each independently of the other hydrogen or a hydroxy-protecting group or together are a bridging hydroxy-protecting group, and Rbis a carboxy-protecting group, which methods are carried out by conversion of the intermediate of formula XIX wherein Raand Rcare each independently of the other hydrogen or a hydroxy-protecting group, and Rbis a carboxy-protective group

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Beilstein Database;Beilstein Institut zur Foerderung der Chemischen Wissenschaften, Beilstein database No. XP-002199750; [Marie-Pierre Heck, Alain Wagner, and Charles Mioskowski,Conversion of Primary Amides to Nitriles by Aldehyde-Catalyzed Water Transfer, J. Org. Chem. 1996, vol. 61,. No. 19, pp. 6486-6487].
Beilstein Database;Beilstein Institut zur Foerderung der Chemischen Wissenschaften, Beilstein database No. XP-002186065; Beilstein Registry No. 6798562; 4 pages; [Tetrahedron Lett.;EN; 35; 12; 1994; 1999-2002].
Beilstein Database;Beilstein Institut zur Foerderung der Chemischen Wissenschaften, database No. XP-002186064; Beilstein Registry No. 1726574; 5 pages; 1957.
Beilstein Database;Beilstein Institut zur Foerderung der Chemischen Wissenschaften, database No. XP-001038115; [D. W. Brooks, et al.,Remote Substituent Effects in Microbial Reductions of 3-Ketoglutarate and 3 Ketoadipate Esters, Tetrahedron Letters, vol. 25, No. 41, pp. 4623-4626, 1984].
Beilstein Database;Beilstein Institut zur Foerderung der Chemischen Wissenschaften, database No. XP-001038113;[R. Roy, et al.,Chemenzymatic Synthesis of A C5-Chiral Building Block: A Substrate Modification Approach, Tetrahedron Letters, vol. 28, No. 42, pp. 4935-4938, 1987].
Beilstein Database;Beilstein Institut zur Foerderung der Chemischen Wissenschaften, database No. XP-002217821; 1page 1904.
Beilstein Database;Beilstein Institut zur Foerderung der Chemischen Wissenschaften, database No. XP-000608147; [K. L. Baumann, et al.,The Convergent Synthesis of CI-981, An Optically Active, Highly Posue Selective Inhibitor of HMG-COA Reductase, Tetrahedron Letters, vol. 33, No. 17, pp. 2283-2284, 1992].
Beilstein Database;Beilstein Institut zur Foerderung der Chemischen Wissenschaften, database No. XP-000608146; [P. L. Brower, et al.,The Synthesis of(4r-Cis)-1, 1-Dimethylethyl 6-Cyanomethyl-2,2-Dimethyl L-1,3-Dioxane-4-Acetate, A Key Intermediate for the Preparation of CI-981, A Highly Potent, Tissue Selective Inhibitor of HMG-COA Reductase, Tetrahedron Letters, vol. 33, No. 17, pp. 2279-2282, Apr. 21, 1992].

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