Process for the preparation of 5-halo-6,9 .alpha.-oxido-prostagl

Chemistry: electrical and wave energy – Processes and products

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204 72, 204 78, 204 79, 204 81, 26034622, C25B 302, C25B 306, C07D30777

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active

042331218

ABSTRACT:
The invention concerns a new process for the preparation of 5-halo-6,9.alpha.-oxido-prostaglandin derivatives of the general formula II ##STR1## wherein R.sup.1 represents a hydrogen atom, an alkyl group optionally substituted by aryl, amino, hydroxyl or a halogen atom, an equivalent of a pharmaceutically acceptable organic or inorganic cation or a conventional hydroxyl protecting group;

REFERENCES:
patent: 3427235 (1969-02-01), Le Duc
patent: 4125712 (1978-11-01), Axen
Chem. Biochem., and Pharmacological Activity of Prostanoids, Roberts et al., p. 290, pub. by Pergamon, N.Y., 1979.
Mech. of Oxidation of Org. Cpds. by Waters, pp. 49-51, pub. by Methuen, London, 1964.
Intro. to Org. Electrochem, by Rifi et al., 1974, pp. 282, 298-307, pub. by Marcel Dekker, New York.
Tamoskozi et al., Tetrahedron Letters, 1977, pp. 2627, 2628.

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