Process for the preparation of 4,4'-diamino-1,1'-dianthrimides

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C01C 5016

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044527420

ABSTRACT:
Process for the preparation of 4,4'-diamino-1,1'-dianthrimides, characterized in that a mixture of an optionally substituted 1,4-diaminoanthraquinone and an optionally substituted 1-aminoanthraquinone in 30-60% strength H.sub.2 SO.sub.4, preferably 40-60% strength H.sub.2 SO.sub.4, is oxidized with peroxomonosulphuric acid or peroxodisulphuric acid, which are preferably employed in the form of the alkali metal or ammonium salts, and the product is then reduced.

REFERENCES:
patent: 1994622 (1935-03-01), Schmidt et al.
patent: 2454679 (1948-11-01), Smyth
patent: 2590825 (1952-03-01), Scalera et al.
patent: 3194820 (1965-07-01), Grelat
The Merck Index, 8 ed. 1968, Stecher et al., editor, pp. 212.
The Chemistry of Synthetic Dyes, vol. II, 1952, Venkatoraman, pp. 892-895.

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