Process for the preparation of 3-alkyl-substituted glutaric acid

Details Process for the preparation of 3-alkyl-substituted glutaric acid Process for the preparation of 3-alkyl-substituted glutaric acid

1982-09-30

1988-04-19

Garner, Vivian

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acids and salts thereof

562528, 562590, 562593, 568346, C07C 51245, C07C 5502

Patent

active

047391146

ABSTRACT:
This invention relates to a novel method of preparing 3-alkyl-substituted glutaric acids and 2-alkyl-substituted succinic acids from 5-alkyl-substituted-1,3-cyclohexane-diones or 3-alkyl-substituted-5-ketohexanoic acids via transition-metal catalyzed oxidation.

REFERENCES:
patent: 2005183 (1935-06-01), Flemming et al.
patent: 2299013 (1942-10-01), Flemming et al.
patent: 2920087 (1960-01-01), Hoy
patent: 4018827 (1977-04-01), Rao et al.
patent: 4340753 (1982-07-01), Cella
March, Jerry, Advanced Organic Chemistry, Second Edition, New York: McGraw-Hill Book Company, 1977, pp. 1089-1090.
Wagner et al, Synthetic Organic Chemistry, New York: John Wiley & Sons, Inc., 1953, p. 420.
R. H. Young, Chem. Comm., 704 (1970).
Beutel, J. Am. Chem. Soc., vol. 93, p. 2615 (1971).

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