Process for the preparation of 2 2 2 trifluoroethanol

Details Process for the preparation of 2 2 2 trifluoroethanol Process for the preparation of 2 2 2 trifluoroethanol

1996-07-26

1997-05-13

Geist, Gary

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

570134, C07C 2970

Patent

active

056294581

ABSTRACT:
A vapor phase process for producing a fluorinated alcohol, such as 2,2,2-trifluoroethanol via oxidation of an hydrofluorocarbon, such as 1,1,1-trifluoroethane, with an oxidizing agent and elemental fluorine.

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patent: 4647786 (1987-03-01), Cheminal et al.
W.T. Miller, Jr. and A.L. Dittman. "The Mechanism of Fluorination. I." J. Amer. Chem. Soc., Jun. 20, 1956, p. 2793.
F.J. Dillemuth et al. "Reaction of Ozone with 1,1-difluoroethane and 1,1,1-Trifluoroethane" J. Phys. Chem., vol. 80, No. 6 (1976) p. 571.
A.L. Henne and M.W. Renoll. "Fluoroethanes and Fluoroethylenes. V." J. Am. Chem. Soc. (Jun., 1936) p. 889.
D.R. Allen. "Preparation of Trifluoroacetic Acid" J. Org. Chem. vol. 26, (Mar., 1961) p. 923.

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