Process for the preparation of 1-oxo-phospholane-chloro-hydrins

Chemistry of carbon compounds – Dipeptides – e.g. – aspartame – anserine – carnosine – etc.

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260936, 568 12, C07F 932, C07F 953

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043293034

ABSTRACT:
1-Oxo-phospholane-chlorohydrins are prepared by reacting 1-oxo-phospholenes with chlorine in the presence of bases which bond hydrogen chloride in a molar ratio of about 1:1:1 in water; the water is optionally in mixture with a water-miscible inert organic solvent. Most of the reaction products are new compounds, which are chiefly used as intermediate products in the field of plastics, of hydraulic fluids and of catalysts for converting isocyanates into carbodiimides.

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patent: 4080385 (1978-03-01), Block
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Houben-Weyl, Band V/3, (1962) pp. 768-771.
Weissberger, Heterocyclic Compounds with Three-Space and Four-Membered Rings, Part 1 (1964), pp. 95-97.
Arbuzov et al., Izv. Aked. Nauk. SSSR 1968, pp. 1237 et seq.

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