Process for the preparation of 1-azidoaldoses

Details Process for the preparation of 1-azidoaldoses Process for the preparation of 1-azidoaldoses

1985-06-28

1987-04-21

Brown, Johnnie R.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carbohydrates or derivatives

536 55, 536124, 536 553, C07H 100

Patent

active

046598103

ABSTRACT:
1-Azidoaldoses are obtained by reacting 1-fluoroaldoses with metal azides in polar, water-miscible, preferably water-containing, solvents. The hydroxyl groups do not react at the same time, so that they need not be protected or can be present in a derivatized form.

REFERENCES:
patent: 4220643 (1980-09-01), Suami
F. Micheel et al., Chem. Bev., 90, 1595 (1957).
A. Bertho, Che. Bev., 63, 841 (1930).
A. Bertho and D. Aures, Liebigs Ann. Chem., 592, 54 (1955).
Micheel, "Chem. Ber.", vol. 88, No. 4, 1955, pp. 475-479.

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