Process for the preparation of 1,1,1,3,3-pentafluoropropane...

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

Reexamination Certificate

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C570S161000, C570S176000

Reexamination Certificate

active

07659435

ABSTRACT:
A process is disclosed for the manufacture of CF3CH2CHF2and CF3CHFCH2F. The process involves (a) reacting hydrogen fluoride, chlorine, and at least one halopropene of the formula CX3CCl═CClX (where each X is independently F or Cl) to produce a product including both CF3CCl2CClF2and CF3CClFCCl2F; (b) reacting CF3CCl2CClF2and CF3CClFCCl2F produced in (a) with hydrogen to produce a product including both CF3CH2CHF2, and CF3CHFCH2F; and (c) recovering CF3CH2CHF2and CF3CHFCH2F from the product produced in (b). In (a), the CF3CCl2CF3and CF3CClFCClF2are produced in the presence of a chlorofluorination catalyst including (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and/or (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.

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