Process for the polymerization of 4-vinyl pyridine monomers

Radiation imagery chemistry: process – composition – or product th – Transfer procedure between image and image layer – image... – Diffusion transfer process – element – or identified image...

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430941, 524459, 526265, 526202, 546329, 546352, C08L 108, C08L 7700

Patent

active

058612300

ABSTRACT:
There is described a novel process of polymerizing 4-vinyl pyridine monomer in an aqueous polymerization system which comprises preparing an aqueous solution of polyvinyl alcohol, and contacting said aqueous solution of a polyvinyl alcohol with less than about 10% by weight of 4-vinyl pyridine monomer and a water-soluble initiator capable of decomposing to give free radicals.
The resultant dispersion of the novel polymerization process comprises a homogeneous, i.e., weight average molecular weight and particle size, poly-4-vinylpyridine, with no appreciable residual 4-vinyl pyridine monomer.
The resultant dispersion may be used to coat image- and ink-receiving layers of image-recording materials and ink jet recording sheets, respectively.

REFERENCES:
patent: 3148061 (1964-09-01), Haas
patent: 3208964 (1965-09-01), Valle, Jr.
patent: 3507846 (1970-04-01), Haas
patent: 4080346 (1978-03-01), Bedell
patent: 4346202 (1982-08-01), Cohen
patent: 4788242 (1988-11-01), Takahashi
patent: 5294686 (1994-03-01), Fiarman

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