Process for the polymerisation of alpha-olefins using a cocataly

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526142, 526153, 526 3, 526351, C08F 464

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058247548

ABSTRACT:
Cocatalytic composition resulting from bringing an organoaluminium halide (A) into contact with an electron-donating organic compound (ED) selected from esters, amides and ketones, the organoaluminium halide (A) possessing an atomic ratio halogen (X)/aluminium (Al) of greater than 1 and less than 1.3, the halide (A) and the compound (ED) being employed in a mole ratio halide (A)/compound (ED) of greater than 20. Catalytic systems which are usable for the polymerization of alpha-olefins, comprising such a cocatalytic composition and a solid based on titanium trichloride complexed with an electron-donating compound.

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