Process for the oxidation of unsaturated aliphatic hydrocarbons

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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5602411, 560246, 562524, 562544, 562548, 562549, 568397, 5683988, 568400, 5684699, 568475, C07C 5125, C07C 5109, C07C 2712, C07C 4532, C07C 4534, C07C 4535, C07C 4537

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044206348

ABSTRACT:
The invention relates to a process for the oxidation of unsaturated hydrocarbons, particularly butenes and isobutylene, for the production of acetic acid, propionic acid and acetone. Specifically the invention comprises the highly selective oxidation of an unsaturated hydrocarbon or of a mixture of unsaturated hydrocarbons in the presence of a catalyst consisting of a complex of trivalent cobalt and of a carbonyl compound, of the aldehydic or ketonic type.

REFERENCES:
patent: 3337618 (1967-08-01), Fariss
patent: 3505400 (1970-04-01), Kronig et al.
patent: 3875225 (1975-04-01), Hobbs et al.

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