Process for the oxidation of secondary-alkyl substituted benzene

Details Process for the oxidation of secondary-alkyl substituted benzene Process for the oxidation of secondary-alkyl substituted benzene

1983-02-23

1984-05-22

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568573, 568569, C07C17902

Patent

active

044503032

ABSTRACT:
High selectivities (>90%) for the production of secondary-alkyl substituted benzene hydroperoxides are achieved by heating a secondary-alkyl substituted benzene in the presence of oxygen and a samarium salt. Preferably, a free radical initiator is also present.

REFERENCES:
patent: 2655545 (1953-10-01), Bruning et al.
patent: 3592857 (1971-07-01), Shinohara
patent: 4282383 (1981-08-01), Dai et al.

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