Process for the oxidation of primary and secondary alcohols to a

Details Process for the oxidation of primary and secondary alcohols to a Process for the oxidation of primary and secondary alcohols to a

1994-12-16

1996-04-23

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568426, 568420, 568404, 568 41, 549498, 549398, 549 32, 546301, 552544, 552576, 548494, 564343, 564453, C07C 4529

Patent

active

055105386

ABSTRACT:
A process for the selective oxidation of a primary or secondary alcohol to an aldehyde or ketone and for the oxidation of a 1,2-diol to an .alpha.-ketol or .alpha.-diketone, which comprises contacting the alcohol or 1,2-diol with o-iodoxybenzoic acid. This process is suited for selective oxidation of alcohols containing easily oxidizable groups, such as amino or thioether groups and easily oxidizable heterocycles.

REFERENCES:
Barton et al, Tetrahedron Letters, vol. 23, pp. 957-960 (1982).
Dess et al, J. Org. Chem., vol. 48, pp. 4155-4156 (1983).
Dess et al, J.A.C.S., vol. 113, pp. 7277-7287 (1991).

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