Process for the oxidation of primary allylic and benzylic alcoho

Details Process for the oxidation of primary allylic and benzylic alcoho Process for the oxidation of primary allylic and benzylic alcoho

1979-12-05

1981-11-03

Helfin, Bernard

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568460, 568445, 568446, 2603478, C07C 4529

Patent

active

042987628

ABSTRACT:
Improved conversions of primary allylic and benzylic alcohols are obtained in an Oppenauer oxidation process, under Oppenauer oxidation conditions, by carrying out the oxidation employing furfural as the hydrogen acceptor. Primary alcohols to which the present invention relates are allylic alcohols substituted in at least the 2-position with a hydrocarbon radical and benzylic alcohols.

REFERENCES:
patent: 2801266 (1957-07-01), Schinz
patent: 4055601 (1977-10-01), Ehmann
Djerassi (I), Organic Reactions, vol. VI (1951), pp. 222-224, 266-267, 208-209.
Adkins et al., J.A.C.S., vol. 71 (1949), pp. 3622-3629.
Batty et al., Chemical Society (London) Journal (1938), pp. 175-179.
Rekasheva et al., Chemical Abstracts, vol. 46 (1952) 1965(d).
Wilds, Organic Reactions, vol. II (1944), pp. 178-179.

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