Process for the oxidation of alpha-olefins

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568470, C07C 4533

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active

046616420

ABSTRACT:
A process for the oxidation of alpha-olefins having from 3 to about 30 carbon atoms, in which the alpha-olefin and molecular oxygen are contacted in the presence of a solution of a Group VIII metal complex containing at least one NO.sub.2 or NO ligand, a divalent copper salt and a tertiary alcohol as solvent.

REFERENCES:
patent: 4323562 (1982-03-01), Tovrog et al.
patent: 4521631 (1985-06-01), Nishimura et al.
Tovrog et al., J. Amer. Chem. Soc., vol. 102 (1980) pp. 6616-6618.
Sndrews et al. J. Amer. Chem. Soc., vol. 103 (1981) pp. 2894-2896.
Henry et al. Publishing Co. (1974) p. 4, Palladium Catalyzed Oxidation of Hydrocarbons.

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