Process for the oxidation of alcohols to acids

Organic compounds -- part of the class 532-570 series – Organic compounds – Fatty compounds having an acid moiety which contains the...

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5625122, 562538, 562540, 554136, 554207, C09F 702

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active

051223082

ABSTRACT:
The instant invention relates to a process for the oxidation of primary alcohols to the corresponding acids, which comprises contacting and thereby reacting an alcohol with a tertiary amine oxide compound at elevated temperatures in the presence of a homogeneous oxidation catalyst comprising a Group VIII metal and a promoter comprising a quaternary ammonium bromide, and subsequently separating out acids from the reaction mixture product.

REFERENCES:
patent: 3818060 (1974-06-01), Forster et al.
patent: 3997578 (1976-12-01), Sheng
patent: 4015060 (1977-03-01), Karayannis et al.
patent: 4096196 (1978-06-01), Boudakian
patent: 4207310 (1980-06-01), Langford
patent: 4225694 (1980-09-01), Dalton et al.
patent: 4996007 (1991-02-01), Caro et al.

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